The problems caused by Arsenic contamination from CCA (Copper Chrome Arsenate) fade into insignificance when compared to arsenic contamination of drinking water in the Third World.
(Sunday Telegraph 5th April 1998 - Bangladesh irrigation wells sunk into bedrock with raised levels of naturally occuring arsenic, put millions at risk)
Arsenic in drinking water is a known public health danger and poses a significant cancer risk. In the US the Safe Drinking Water Act Amendments of 1996 require the EPA to propose a revised standard by 1st Jan 2000.
The existing US standard of 50 ppb for arsenic in public water supplies, will be revised by 1st Jan 2000 (possibly to within the 2 to 5 ppb).
The new WHO limit has been revised down to 10 ppb. This will be the new EC limit from 2003.
In surface waters the most common ionic valance state of arsenic is As (V) or arsenate. As (III) or arsenite, the most toxic form, is more likely to occur in anaerobic ground waters (well water). In the pH range of 4 to 10, the predominant As (III) compound is neutral in charge, while the As (V) species are negatively charged. Most removal technologies are based on chemical charge; therefore removal efficiencies for As (III) are poor compared to removal of As (V).
The Current Best Available Technologies in the US for arsenic removal are most effective in treating As (V). As (III) can be converted to As (V) using chlorine, potassium permanganate, hydrogen peroxide and ozone.
- Coagulation/Filtration (CF)
The traditional process for removal of particulate and As (V). The major drawback is the disposal of by-product sludge.
- Lime Softening (LS)
Problem of disposal by-product sludge, however secondary treatment is required to meet 2 ppb std.
- Activated Alumina (AA)
Most effective at removing As (V) at a pH of 6. Highly concentrated hazardous waste by-streams produced during regeneration.
- Ion Exchange (IX)
Uneconomic for sulphate levels above 200 ppm. Highly concentrated hazardous waste by-product stream.
- Membrane Filtration (MF); Reverse Osmosis (RO) and Nanofiltration (NF) and Ultrafiltration (UF)
Stainless steel and PVC materials may be required for corrosion resistance. 20-25% water rejection, large volumes of arsenic contaminated reject water are a possible disposal issue.
- Lanthanum Oxide/Silica (LaSi)
Selectively adsorbs both As (III) and As(V). LaSi is a new product, needs pilot testing to confirm capital and operating costs. Highly concentrated, low volume waste streams are produced requiring sophisticated process control and safe arsenic residue disposal.
Michael J Brooks
EnviroMet Consultants